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Iridium Bifunctional Ligand Tetrabutylammonium (4’methyl-[2,2’bipyridin]-5yl)methanesulfonate Small Molecule (Tool Compound)

Invented at University of Cambridge

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Relevance Tetrabutylammonium (4’methyl-[2,2’bipyridin]-5yl)methanesulfonate is a small molecule that has been shown to act as a bifunctional ligand for iridium to control regioselectivity of iridium-catalysed borylation on cationic substrates.
Research Area Drug Discovery & Development

References

There are 2 reference entries for this reagent.

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References: 2 entries

Davis et al. 2016. J Am Chem Soc. 138(39):12759-12762. PMID: 27626468.

Ion Pair-Directed Regiocontrol in Transition-Metal Catalysis: A Meta-Selective C-H Borylation of Aromatic Quaternary Ammonium Salts.

Europe PMC ID: 27626468


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References: 2 entries

Davis et al. 2016. J Am Chem Soc. 138(39):12759-12762. PMID: 27626468.

Ion Pair-Directed Regiocontrol in Transition-Metal Catalysis: A Meta-Selective C-H Borylation of Aromatic Quaternary Ammonium Salts.


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